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An overview and recent advances in electrocatalysts for direct seawater splitting

《化学科学与工程前沿（英文）》 2021年 第15卷 第6期   页码 1408-1426 doi: 10.1007/s11705-021-2102-6

摘要： In comparison to pure water, seawater is widely accepted as an unlimited resource. The direct seawater splitting is economical and eco-friendly, but the key challenges in seawater, especially the chlorine-related competing reactions at the anode, seriously hamper its practical application. The development of earth-abundant electrocatalysts toward direct seawater splitting has emerged as a promising strategy. Highly efficient electrocatalysts with improved selectivity and stability are of significance in preventing the interference of side reactions and resisting various impurities. This review first discusses the macroscopic understanding of direct seawater electrolysis and then focuses on the strategies for rational design of electrocatalysts toward direct seawater splitting. The perspectives of improved electrocatalysts to solve emerging challenges and further development of direct seawater splitting are also provided.

关键词： seawater splitting     electrocatalysts     oxygen evolution reaction     hydrogen evolution reaction     chlorine chemistry    

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strong>x nanosheets on Ni foam as an electrocatalyst for efficient overall alkaline seawatersplitting

《化学科学与工程前沿（英文）》 2023年 第17卷 第11期   页码 1698-1706 doi: 10.1007/s11705-023-2334-8

摘要： The electrocatalyst NiFeRuOx/NF, comprised of NiFeRuOx nanosheets grown on Ni foam, was synthesized using a hydrothermal process followed by thermal annealing. NiFeRuOx/NF displays high electrocatalytic activity and stability for overall alkaline seawater splitting: 98 mV@ 10 mA∙cm−2 in hydrogen evolution reaction, 318 mV@ 50 mA∙cm−2 in oxygen evolution reaction, and a cell voltage of 1.53 V@ 10 mA∙cm−2, as well as 20 h of durability. A solar-driven system containing such a bifunctional NiFeRuOx/NF has an almost 100% Faradaic efficiency. The NiFeRuOx coating around Ni foam is an anti-corrosion layer and also a critical factor for enhancement of bifunctional performances.

关键词： NiFeRuOx nanosheets     Ni foam     electrocatalysis     overall seawater splitting     solar-driven system    

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Nonlinear sealing force of a seawater balance valve used in an 11000-meter manned submersible

《机械工程前沿（英文）》 2023年 第18卷 第1期 doi: 10.1007/s11465-022-0726-y

摘要： Balance valve is a core component of the 11000-meter manned submersible “struggle,” and its sealing performance is crucial and challenging when the maximum pressure difference is 118 MPa. The increasing sealing force improves the sealing performance and increases the system’s energy consumption at the same time. A hybrid analytical–numerical–experimental (ANE) model is proposed to obtain the minimum sealing force, ensuring no leakage at the valve port and reducing energy consumption as much as possible. The effects of roundness error, environmental pressure, and materials on the minimum sealing force are considered in the ANE model. The basic form of minimum sealing force equations is established, and the remaining unknown coefficients of the equations are obtained by the finite element method (FEM). The accuracy of the equation is evaluated by comparing the independent FEM data to the equation data. Results of the comparison show good agreement, and the difference between the independent FEM data and equation data is within 3% when the environmental pressure is 0–118 MPa. Finally, the minimum sealing force equation is applied in a balance valve to be experimented using a deep-sea simulation device. The balance valve designed through the minimum sealing force equation is leak-free in the experiment. Thus, the minimum sealing force equation is suitable for the ultrahigh pressure balance valve and has guiding significance for evaluating the sealing performance of ultrahigh pressure balance valves.

关键词： seawater balance valve     sealing performance     hybrid ANE model     FEM     minimum sealing force equation    

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Compressive behavior and microstructure of concrete mixed with natural seawater and sea sand

《结构与土木工程前沿（英文）》 2021年 第15卷 第6期   页码 1347-1357 doi: 10.1007/s11709-021-0780-2

摘要： Noncorrosive reinforcement materials facilitate producing structural concrete with seawater and sea sand. This study investigated the properties of seawater and sea sand concrete (SSC), considering the curing age (3, 7, 14, 21, 28, 60, and 150 d) and strength grade (C30, C40, and C60). The compressive behavior of SSC was obtained by compressive tests and digital image correction (DIC) technique. Scanning electron microscope (SEM) and X-ray powder diffraction (XRD) methods were applied to understand the microstructure and hydration products of cement in SSC. Results revealed a 30% decrease in compressive strength for C30 and C40 SSC from 60 to 150 d, and a less than 5% decrease for C60 from 28 to 150 d. DIC results revealed significant cracking and crushing from 80% to 100% of compressive strength. SEM images showed a more compact microstructure in higher strength SSC. XRD patterns identified Friedel’s salt phase due to the chlorides brought by seawater and sea sand. The findings in this study can provide more insights into the microstructure of SSC along with its short- and long-term compressive behavior.

关键词： seawater and sea sand concrete     compressive strength     strain field     microstructure     hydration products    

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Effect of seawater salinity on the synthesis of zeolite from coal fly ash

Yanqing YU, Xiaoliang LI, Xiaolan ZOU, Xiaobin ZHU

《环境科学与工程前沿（英文）》 2014年 第8卷 第1期   页码 54-61 doi: 10.1007/s11783-013-0493-4

摘要： A novel method for the synthesis of zeolite was developed in this paper. The synthesis was carried out by hydrothermal activation after alkali fusion and coal fly ash (CFA) was used as raw material with seawater of different salinities. Seawater salinity was varied from 32 to 88 for zeolite crystallization during the hydrothermal process. The results show that seawater salinity plays an important role in zeolite synthesis with CFA during hydrothermal treatment. The products were a mixture of NaX zeolite and hydroxysodalite; seawater salinity more strongly affected the crystallization than the type and chemical composition of the zeolites. The yield of CFA transformed into zeolite gradually rose with the increase in salinity, reaching a transformation rate of 48%–62% as the salinity increased from 32 to 88, respectively. The proposed method allows for the efficient disposal of by-products; therefore, the application of seawater in zeolite synthesis presents promising economic and ecological benefits.

关键词： coal fly ash (CFA)     seawater salinity     zeolite synthesis    

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A “Seawater-in-Sludge” approach for capacitive biochar production via the alkaline and alkaline earth

Xiling Li, Tianwei Hao, Yuxin Tang, Guanghao Chen

《环境科学与工程前沿（英文）》 2021年 第15卷 第1期 doi: 10.1007/s11783-020-1295-0

摘要： Abstract • Capacitive biochar was produced from sewage sludge. • Seawater was proved to be an alternative activation agent. • Minerals vaporization increased the surface area of biochar. • Molten salts acted as natural templates for the development of porous structure. Sewage sludge is a potential precursor for biochar production, but its effective utilization involves costly activation steps. To modify biochar properties while ensuring cost-effectiveness, we examined the feasibility of using seawater as an agent to activate biochar produced from sewage sludge. In our proof-of-concept study, seawater was proven to be an effective activation agent for biochar production, achieving a surface area of 480.3 m2/g with hierarchical porosity distribution. Benefited from our design, the catalytic effect of seawater increased not only the surface area but also the graphitization degree of biochar when comparing the pyrolysis of sewage sludge without seawater. This leads to seawater activated biochar electrodes with lower resistance, higher capacitance of 113.9 F/g comparing with control groups without seawater. Leveraging the global increase in the salinity of groundwater, especially in coastal areas, these findings provide an opportunity for recovering a valuable carbon resource from sludge.

关键词： Sewage sludge     Biochar     Seawater     Recourse recovery     Capacitor    

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Generation of enhanced stability of SnO/In(OH)/InP for photocatalytic water splitting by SnO protection

《能源前沿（英文）》 2021年 第15卷 第3期   页码 710-720 doi: 10.1007/s11708-021-0764-x

摘要： InP shows a very high efficiency for solar light to electricity conversion in solar cell and may present an expectation property in photocatalytic hydrogen evolution. However, it suffers serious corrosion in water dispersion. In this paper, it is demonstrated that the stability and activity of the InP-based catalyst are effectively enhanced by applying an anti-corrosion SnO layer and In(OH)3 transition layer, which reduces the crystal mismatch between SnO and InP and increases charge transfer. The obtained Pt/SnO/In(OH)3/InP exhibits a hydrogen production rate of 144.42 µmol/g in 3 h under visible light illumination in multi-cycle tests without remarkable decay, 123 times higher than that of naked In(OH)3/InP without any electron donor under visible irradiation.

关键词： SnO/In(OH)3/InP photocatalyst     enhanced activity and stability for water splitting     corrosion inhibition     enhancing charge transfer and decreasing crystal mismatch    

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Approaching the commercial threshold of solar water splitting toward hydrogen by III-nitrides nanowires

《能源前沿（英文）》 doi: 10.1007/s11708-023-0870-z

摘要： Approaching the commercial threshold of solar water splitting toward hydrogen by III-nitrides nanowires

关键词： threshold solar water     splitting hydrogen III    

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Water pumping analysis and experimental validation of beach well infiltration intake system in a seawater

Huan ZHANG,Shu LIU,Xuejing ZHENG,Gaofeng CHEN

《能源前沿（英文）》 2015年 第9卷 第3期   页码 335-342 doi: 10.1007/s11708-015-0365-7

摘要： Based on energy conservation equation and Darcy’s law, a model of beach well infiltration intake system applied in a seawater source heat pump system was established. The model consists of the seawater seepage and the heat transfer process. A porous medium model in a software named FLUENT was applied to simulate the seepage and the heat transfer process. This model was also validated by field experiment conducted on the seashore in Tianjin, China. The maximum relative error between simulation results and experimental results was 2.1% (less than 5%), which was acceptable in engineering application. The porosity and coefficient of thermal conductivity of the aquifer soil were determined to be 0.49 W/(m·K) and 1.46 W/(m·K), respectively in the simulation. In addition, the influencing factors of pumping water of beach well were also analyzed. The pumping water was found to increase when the distance between the beach well and the impervious boundary becomes longer, when the distance between the beach well and the supplying water source shortens, when the diameter of the beach well enlarges, and the drawdown enlarges.

关键词： water pumping analysis     experimental validation     infiltration intake system     seawater source heat pump    

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Acoustic emissions evaluation of the dynamic splitting tensile properties of steel fiber reinforced concrete

《结构与土木工程前沿（英文）》   页码 1341-1356 doi: 10.1007/s11709-023-0988-4

摘要： This study empirically investigated the influence of freeze–thaw cycling on the dynamic splitting tensile properties of steel fiber reinforced concrete (SFRC). Brazilian disc splitting tests were conducted using four loading rates (0.002, 0.02, 0.2, and 2 mm/s) on specimens with four steel fiber contents (0%, 0.6%, 1.2%, and 1.8%) subjected to 0 and 50 freeze–thaw cycles. The dynamic splitting tensile damage characteristics were evaluated using acoustic emission (AE) parameter analysis and Fourier transform spectral analysis. The results quantified using the freeze–thaw damage factor defined in this paper indicate that the degree of damage to SFRC caused by freeze–thaw cycling was aggravated with increasing loading rate but mitigated by increasing fiber content. The percentage of low-frequency AE signals produced by the SFRC specimens during loading decreased with increasing loading rate, whereas that of high-frequency AE signals increased. Freeze–thaw action had little effect on the crack types observed during the early and middle stages of the loading process; however, the primary crack type observed during the later stage of loading changed from shear to tensile after the SFRC specimens were subjected to freeze–thaw cycling. Notably, the results of this study indicate that the freeze–thaw damage to SFRC reduces AE signal activity at low frequencies.

关键词： steel fiber reinforced concrete     freeze–thaw cycling     Brazilian disc splitting test     acoustic emission technique     dynamic splitting tensile acoustic emission properties    

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海水淡化技术与太阳能利用

张耀明,邹宁宇

《中国工程科学》 2005年 第7卷 第11期   页码 37-41

摘要：

海水淡化是解决水源危机的根本措施，但海水淡化绝不能以牺牲能源为代价；现有的几种海水淡化技术各有优劣，应配套使用；河海大学和南京玻纤院等研制的太阳能加热装置，可以作为海水淡化装置中清洁、无污染的能源。

关键词： 海水淡化     太阳能     定日镜     能源     水源    

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Enhanced photocatalytic water splitting with surface defective SrTiO

Junying LIU, Zhidong WEI, Wenfeng SHANGGUAN

《能源前沿（英文）》 2021年 第15卷 第1期   页码 700-709 doi: 10.1007/s11708-021-0735-2

摘要： Surface reconstructed SrTiO nanocrystals were synthesized by a thermal treatment process in presence of NaBH and SrTiO nanocrystals. The surface reconstruction of SrTiO nanocrystals is attributed to the introduction of surface oxygen vacancies or Ti sites (such as Ti and Ti ) during the hydrogenation treatment process. The light absorption and the charge transfer ability of SrTiO nanocrystals are simultaneously enhanced due to surface oxygen vacancies or Ti sites (such as Ti and Ti ), which are beneficial to photocatalytic water splitting. Meanwhile, these defects also change the redox potential of the photocatalysts. Since there existed a synergistic effect between the three, the ratio of hydrogen to oxygen production was also regulated.

关键词： SrTiO3     surface reconstruction     oxygen vacancies     photocatalytic water splitting    

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polarization enhanced bismuth ferrate photoelectrode: fabrication and boosted photoelectrochemical water splitting

《能源前沿（英文）》 2021年 第15卷 第3期   页码 781-790 doi: 10.1007/s11708-021-0782-8

摘要： In this paper, the fabrication of a highly orientated Bi2Fe4O9 (BFO) photoelectrode in the presence of two-dimensional (2D) graphene oxide (GO) was reported. It was found that the GO can be used as a template for controlling the growth of BFO, and the nanoplate composites of BFO/reduced graphene oxide (RGO) with a high orientation can be fabricated. The thickness of the nanoplates became thinner as the ratio of GO increased. As a result, the ferroelectric spontaneous polarization unit arranges itself in the space in a periodic manner, leading to the formation of a polarization field along a special direction. Therefore, the created built-in electric field of the nanoplate composites of BFO/RGO is improved upon the increase of the amount of RGO. As expected, carrier separation is enhanced by the built-in electric field, therefore substantially enhancing the photoelectrochemical (PEC) activity of water splitting compared to pure BFO under the irradiation of visible-light.

关键词： bismuth ferrate     ferroelectric polarisation     photoelectrochemical (PEC) water splitting     graphene oxide (GO)     high orientation    

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Surface modification of mesoporous silica nanoparticle with 4-triethoxysilylaniline to enhance seawater

Jian Wang, Qun Wang, Xueli Gao, Xinxia Tian, Yangyang Wei, Zhen Cao, Chungang Guo, Huifeng Zhang, Zhun Ma, Yushan Zhang

《环境科学与工程前沿（英文）》 2020年 第14卷 第1期 doi: 10.1007/s11783-019-1185-5

摘要： Mesoporous silica nanoparticle was modified with 4-triethoxysilylaniline. AMSN-based TFN-RO membranes were prepared for seawater desalination. Water transport capability of the AMSN was limited by polyamide. Polyamide still plays a key role in permeability of the TFN RO membranes. Mesoporous silica nanoparticles (MSN), with higher water permeability than NaA zeolite, were used to fabricate thin-film nanocomposite (TFN) reverse osmosis (RO) membranes. However, only aminoalkyl-modified MSN and low-pressure (less than 2.1 MPa) RO membrane were investigated. In this study, aminophenyl-modified MSN (AMSN) were synthesized and used to fabricate high-pressure (5.52 MPa) RO membranes. With the increasing of AMSN dosage, the crosslinking degree of the aromatic polyamide decreased, while the hydrophilicity of the membranes increased. The membrane morphology was maintained to show a ridge-and-valley structure, with only a slight increase in membrane surface roughness. At the optimum conditions (AMSN dosage of 0.25 g/L), when compared with the pure polyamide RO membrane, the water flux of the TFN RO membrane (55.67 L/m2/h) was increased by about 21.6%, while NaCl rejection (98.97%) was slightly decreased by only 0.29%. However, the water flux of the membranes was much lower than expected. We considered that the enhancement of RO membrane permeability is attributed to the reduction of the effective thickness of the PA layer.

关键词： Thin film nanocomposite membrane     Reverse osmosis     Seawater desalination     Aminophenyl-functionalized mesoporous silica nanoparticles    

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Ga(X)N/Si nanoarchitecture: An emerging semiconductor platform for sunlight-powered water splitting toward

《能源前沿（英文）》 doi: 10.1007/s11708-023-0881-9

摘要： Sunlight-powered water splitting presents a promising strategy for converting intermittent and virtually unlimited solar energy into energy-dense and storable green hydrogen. Since the pioneering discovery by Honda and Fujishima, considerable efforts have been made in this research area. Among various materials developed, Ga(X)N/Si (X = In, Ge, Mg, etc.) nanoarchitecture has emerged as a disruptive semiconductor platform to split water toward hydrogen by sunlight. This paper introduces the characteristics, properties, and growth/synthesis/fabrication methods of Ga(X)N/Si nanoarchitecture, primarily focusing on explaining the suitability as an ideal platform for sunlight-powered water splitting toward green hydrogen fuel. In addition, it exclusively summarizes the recent progress and development of Ga(X)N/Si nanoarchitecture for photocatalytic and photoelectrochemical water splitting. Moreover, it describes the challenges and prospects of artificial photosynthesis integrated device and system using Ga(X)N/Si nanoarchitectures for solar water splitting toward hydrogen.

关键词： Ga(X)N/Si nanoarchitecture     artificial photosynthesis     water splitting     solar toward hydrogen    

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标题 作者 时间 类型 操作

An overview and recent advances in electrocatalysts for direct seawater splitting

期刊论文

strong>x nanosheets on Ni foam as an electrocatalyst for efficient overall alkaline seawatersplitting

期刊论文

Nonlinear sealing force of a seawater balance valve used in an 11000-meter manned submersible

期刊论文

Compressive behavior and microstructure of concrete mixed with natural seawater and sea sand

期刊论文

Effect of seawater salinity on the synthesis of zeolite from coal fly ash

Yanqing YU, Xiaoliang LI, Xiaolan ZOU, Xiaobin ZHU

期刊论文

A “Seawater-in-Sludge” approach for capacitive biochar production via the alkaline and alkaline earth

Xiling Li, Tianwei Hao, Yuxin Tang, Guanghao Chen

期刊论文

Generation of enhanced stability of SnO/In(OH)/InP for photocatalytic water splitting by SnO protection

期刊论文

Approaching the commercial threshold of solar water splitting toward hydrogen by III-nitrides nanowires

期刊论文

Water pumping analysis and experimental validation of beach well infiltration intake system in a seawater

Huan ZHANG,Shu LIU,Xuejing ZHENG,Gaofeng CHEN

期刊论文

Acoustic emissions evaluation of the dynamic splitting tensile properties of steel fiber reinforced concrete

期刊论文

海水淡化技术与太阳能利用

张耀明,邹宁宇

期刊论文

Enhanced photocatalytic water splitting with surface defective SrTiO

Junying LIU, Zhidong WEI, Wenfeng SHANGGUAN

期刊论文

polarization enhanced bismuth ferrate photoelectrode: fabrication and boosted photoelectrochemical water splitting

期刊论文

Surface modification of mesoporous silica nanoparticle with 4-triethoxysilylaniline to enhance seawater

Jian Wang, Qun Wang, Xueli Gao, Xinxia Tian, Yangyang Wei, Zhen Cao, Chungang Guo, Huifeng Zhang, Zhun Ma, Yushan Zhang

期刊论文

Ga(X)N/Si nanoarchitecture: An emerging semiconductor platform for sunlight-powered water splitting toward

期刊论文